Julia Roberts And Lyle Lovett
Here’s another marriage that shocked everyone in Hollywood. No one anticipated that Julia Roberts and Lyle Lovett would end up falling in love but that was what destiny had in store for them. Love certainly works in mysterious ways, doesn’t it? The country crooner and the Hollywood sweetheart exchanged their vows in 1993.
However, it wasn’t meant to be and they would separate in March 1995.
Brad Pitt and Angelina Jolie
No list about celebrity couples will be complete without Brangelina! Brad Pitt and Angelina Jolie were the biggest stars in Hollywood when they appeared in Mr. and Mrs. Smith as the titular characters.
It certainly felt like destiny when they fell in love with each other while shooting the film! They already had six kids, both adopted and biological, before they got married. They tied the knot in 2014 at Château Miraval in France. Sadly, the power couple decided to break it off in 2016.